Bio-photovoltaic

We receive peak power of 1-1.3 kW/m2 from the sun on a sunny day. It is very desirable to harvest this light, store it, and use it during low light conditions. There are many different designs for solar cells. In this project, we tried to adopt nature’s solution for harvesting light for solar cell application. The project focus was on the design and fabrication of different architectures for utilizing reaction center of Rhodobacter sphaeroides in a solar cell device (Figure A, B). I proposed using electrospraying of RCs on HOPG for fabrication of photo-active electrodes (Figure C). In collaboration with two postdocs and three PhD students at UBC, we could show that the RCs not only survive the electrospray process but also yield peak photocurrent densities that were the highest value reported to the date of publication.

Figure – A) Left: A schematic of the energy levels, recombination time constants, and theoretical ultimate power conversion efficiencies for each cofactor in the R. sphaeroides RC. Right: Crystal structure showing the position of RC cofactors (carotenoid not shown). B) Red and blue field lines represent the negative and positive charges respectively on the surface of the RC. The H subunit is in orange, L in pink, and M in green. BChls are in red, BPhes in yellow, and Qs in blue. C) Topography image of an HOPG surface after RC electrospray and rinsing. One lightly deposited area is displayed to show the contrast between the coated and clean HOPG.

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